A robust Ti(iv)-based mesogen constructed around a TiO4N2 core.

Autor: Barloy, L., Heinrich, B., Douce, L., Henry, M., Scarpi-Luttenauer, M., Kyritsakas, N., Mobian, P.
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 2/14/2019, Vol. 48 Issue 6, p1960-1963, 4p
Abstrakt: Stable complexes [Ti(1a)(2)2] and [Ti(1b)(2)2], where 2 is the 6,6′-diphenyl-2,2′-biphenolato ligand and 1a and 1b ligands are 2,2′-bipyrimidine derivatives, are synthesized. The complex [Ti(1b)(2)2] containing a diimine ligand substituted with long alkyl chains (C16) exhibits a liquid crystal behaviour. This property and self-assembling in the crystalline state are explained by the particular molecular conformation of the complexes. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index