Autor: |
Barloy, L., Heinrich, B., Douce, L., Henry, M., Scarpi-Luttenauer, M., Kyritsakas, N., Mobian, P. |
Předmět: |
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Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 2/14/2019, Vol. 48 Issue 6, p1960-1963, 4p |
Abstrakt: |
Stable complexes [Ti(1a)(2)2] and [Ti(1b)(2)2], where 2 is the 6,6′-diphenyl-2,2′-biphenolato ligand and 1a and 1b ligands are 2,2′-bipyrimidine derivatives, are synthesized. The complex [Ti(1b)(2)2] containing a diimine ligand substituted with long alkyl chains (C16) exhibits a liquid crystal behaviour. This property and self-assembling in the crystalline state are explained by the particular molecular conformation of the complexes. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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