A mono-metallic Pd(ii)-cage featuring two different polar binding sites.

Autor: Escobar, Luis, Villarón, David, Escudero-Adán, Eduardo C., Ballester, Pablo
Předmět:
Zdroj: Chemical Communications; 1/16/2019, Vol. 55 Issue 5, p604-607, 4p
Abstrakt: The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(ii)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index