A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity.

Autor: Kulakova, Alena N., Bilyachenko, Alexey N., Korlyukov, Alexander A., Shul'pina, Lidia S., Bantreil, Xavier, Lamaty, Frédéric, Shubina, Elena S., Levitsky, Mikhail M., Ikonnikov, Nikolay S., Shul'pin, Georgiy B.
Předmět:
Zdroj: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/28/2018, Vol. 47 Issue 44, p15666-15669, 4p
Abstrakt: A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane Ph12Si12O12(OH)(O)11Cu5Na(bipy)3(H2O) exhibited high catalytic efficiency in two homogeneous reactions: (i) functionalization of C–H compounds; (ii) formation of benzamides from alcohols. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index