Rare earth doping and effective band-convergence in SnTe for improved thermoelectric performance.

Autor: Acharya, Somnath, Dey, Dibyendu, Maitra, Tulika, Soni, Ajay, Taraphder, A.
Předmět:
Zdroj: Applied Physics Letters; 11/5/2018, Vol. 113 Issue 19, pN.PAG-N.PAG, 5p, 1 Chart, 5 Graphs
Abstrakt: Thermoelectric performance of SnTe has been found to enhance with isovalent doping of alkaline and transition metal elements where most of these elements have a solubility of less than 13%. We propose a strategy of doping rare earth element Yb to enhance the thermoelectric performance of SnTe. With heavy atomic mass and strong spin-orbit coupling, even the mild doping of Yb (∼5%) is enough to create a degeneracy via band-convergence which enhances the density of states near the Fermi level and improves the overall performance. Our transport data and first-principles calculations corroborate that nearly 5% Yb is an efficient dopant to achieve thermoelectric response which is equivalent to 9% of Mn doping. The results are useful for understanding the environmentally friendly thermoelectric SnTe. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index