| Autor: |
Cary, Samantha K., Su, Jing, Galley, Shane S., Albrecht-Schmitt, Thomas E., Batista, Enrique R., Ferrier, Maryline G., Kozimor, Stosh A., Mocko, Veronika, Scott, Brian L., Van Alstine, Cayla E., White, Frankie D., Yang, Ping |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 11/7/2018, Vol. 47 Issue 41, p14452-14461, 10p |
| Abstrakt: |
Characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)3(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm–S (mean of 2.86 ± 0.04 Å) and Cf–S (mean of 2.84 ± 0.04 Å) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)3(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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