Spectroscopic Study of the Semihydrate of the Dodecahydro-closo-dodecaborate of 2,4,6-Triamino-1,3,5-triazine.

Autor: Saldin, V. I., Slobodyuk, A. B., Savchenko, N. N., Ignat’eva, L. N., Buznik, V. M.
Zdroj: Russian Journal of Physical Chemistry; Nov2018, Vol. 92 Issue 11, p2210-2214, 5p
Abstrakt: Abstract: The presence of directed localized cation-anion interactions in the semihydrate of 2,4,6-triamino-1,3,5-triazine (melamine) dodecahydro-closo-dodecaborate (С3Н6N6Н)2В12Н12 · 0.5Н2О is discovered by means of IR and NMR-spectroscopy (11В, 1Н, С, N). The hypothesis that melamine protonation proceeds on the ring atom of nitrogen is confirmed via quantum-chemical calculations. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index