| Autor: |
Shevchenko, Grigory A., Dehn, Stefanie, List, Benjamin |
| Předmět: |
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| Zdroj: |
Synlett; 2017, Vol. 29 Issue 17, p2298-2300, 3p |
| Abstrakt: |
We report a Brønsted acid mediated direct α-hydroxylation of cyclic α-branched ketones via a tandem aminoxylation/N-O bond-cleavage process. Nitrosobenzene is used as the oxidant and subsequently promotes the liberation of the free alcohol. The desired products could be isolated in moderate to good yields at a maximum tested scale of 10 mmol. Derivatizations of the obtained products are presented. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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