Autor: |
Richardson, Paul, Hsu, Ting-Jung, Kuo, Che-Jung, Holmberg, Rebecca J., Gabidullin, Bulat, Rouzières, Mathieu, Clérac, Rodolphe, Murugesu, Muralee, Lin, Po-Heng |
Předmět: |
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Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 10/7/2018, Vol. 47 Issue 37, p12847-12851, 5p |
Abstrakt: |
Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R3̅ space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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