| Autor: |
Servati, Zahra, Saber-Tehrani, Mandana, Taghvaei-Ganjali, Saeed, Zadmard, Reza |
| Zdroj: |
Journal of Porous Materials; Oct2018, Vol. 25 Issue 5, p1463-1474, 12p |
| Abstrakt: |
This study presents the adsorption behavior of chemically bonded chlorosulfonyl-calix[4]arene to silica gel (CSC[4]A-SiO2) for couples of rubber chemicals additives, diphenylguanidine (DPG), N-cyclohexyl-2-benzothiazolesulfenamide (CBS) and 2-mercaptobenzothiazole (MBT). Results of study showed that CSC[4]A-SiO2 is a selective sorbent for DPG and CBS (as ordinary accelerators in the manufacture of rubber compounds) by means of electrostatic interaction and hydrogen bonding between hydroxyl groups of calix[4]arene moiety and the NH group of DPG and CBS molecules. The batch adsorption study was carried out to evaluate the rubber chemical additives removal efficiency and selectivity of CSC[4]A-SiO2. It was observed that the percentage of DPG and CBS removal reached 49 and 55% in the presence of CSC[4]A-SiO2 respectively. In order to give evidence to the stronger interaction of DPG and CBS with CSC[4]A-SiO2, 1H-NMR studies were performed. We have also discovered that the CSC[4]A-SiO2 can be act as a new auxiliary NMR shift reagent, via a host-guest molecular recognition process. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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