| Autor: |
Ouis, Sakina, Rouag, Djamil Azzedine, Bendjeddou, Lamia, Bailly, Corinne |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Jul2018, Vol. 74 Issue 7, p977-980, 15p |
| Abstrakt: |
In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenyl-phosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H-(C18H15P)2]μC4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]μ(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C-H...O and C-H...π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each PtII atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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