Crystal structure of diethyl {2,2,2-trichloro-1-[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)-4-methylpentanamido]ethyl}phosphonate.

Autor: Brovarets, V. S., Golovchenko, O. V., Rusanov, E. B., Rusanova, J. A.
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications; Jul2018, Vol. 74 Issue 7, p915-917, 9p
Abstrakt: In the title phosphorylated compound, C20H26Cl3N2O6P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3)Å. In the crystal, pairs of molecules are linked by N-H...O and weak C-H...O hydrogen bonds involving the same acceptor atom, forming inversion dimers. In addition, π-π stacking interactions between the phthalimide groups, with a centroid-centroid distance of 3.7736 (13)Å, and further weak C-H...O hydrogen bonds connect the inversion dimers into columns along [0͞11]. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index