Autor: |
Peshkov, Vsevolod A., Pereshivko, Olga P., Nechaev, Anton A., Peshkov, Anatoly A., Van der Eycken, Erik V. |
Předmět: |
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Zdroj: |
Chemical Society Reviews; 6/7/2018, Vol. 47 Issue 11, p3861-3898, 38p |
Abstrakt: |
This focused review aims to summarize recent developments in the processes involving additions of secondary propargylamines to various heteroallenes and subsequent transition metal-catalyzed or electrophile-mediated cyclizations. The utility of this convenient and tunable strategy spans from the carbon dioxide fixation and target-oriented synthesis of complex natural and biologically active products to the generation of extended synthetic libraries of diverse oxygen-, nitrogen- and sulfur-containing heterocycles. For comparative purposes, the analogous transformations of propargylic alcohols are also highlighted in this account. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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