Furan-2-carbaldehydes as C1 building blocks for the synthesis of quinazolin-4(3H)-ones via ligand-free photocatalytic C–C bond cleavage.

Autor: Yu, Wenjia, Zhang, Xianwei, Qin, Bingjie, Wang, Qiyang, Ren, Xuhong, He, Xinhua
Předmět:
Zdroj: Green Chemistry; 6/7/2018, Vol. 20 Issue 11, p2449-2454, 6p
Abstrakt: Furan-2-carbaldehydes, as biomass-derived chemicals, are used as efficient green C1 building blocks to synthesize bioactive quinazolin-4(3H)-ones by ligand-free photocatalytic C–C bond cleavage. Notably, protection of hydroxyl, carboxyl, amide, or secondary amino groups is not required. Mechanistic studies suggest that conjugated N,O-tridentate copper complexes act as novel photoinitiators under visible light. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index