Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer.

Autor: Kim, Myung Hyun, Choi, Jaewon, Ko, Kyoung Chul, Cho, Kyoungil, Park, Ji Hoon, Lee, Sang Moon, Kim, Hae Jin, Ko, Yoon-Joo, Lee, Jin Yong, Son, Seung Uk
Předmět:
Zdroj: Chemical Communications; 5/18/2018, Vol. 54 Issue 40, p5134-5137, 4p
Abstrakt: Hollow and microporous organic network bearing alkynone moieties was prepared via carbonylative Sonogashira coupling. The carbonyl groups in the network showed unusual chemical reactivities, compared with those of a model alkynone compound. The observed differences between the reactivities of alkynones in the molecule and in the network were analyzed based on the “network effect”. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index