Perturbation of the NH2 pKa Value of Adenine in Platinum(II) Complexes: Distinct Stereochemical Internucleobase Effects ( Abbreviations: 9EtA=9-ethyladenine, 9MeA=9-methyladenine, 9MeA-=9-methyladenine anion, 9MeAH+=9-methyladeninium, 1MeU=1-methyluracil anion, 1MeC=1-methylcytosine, 9EtGH=9-ethylguanine, 9MeGH=9-methylguanine, 1MeT=1-methylthymine anion, A=adenine nucleobases, GH=guanine nucleobases, C=cytosine nucleobases, U=uracil anion nucleobases, T=thymine anion nucleobases, a=NH3, ma=CH3NH2. )

Autor: Marta Garijo Añorbe, Marc Sven Lüth, Michael Roitzsch, Marta Morell Cerdà, Patrick Lax, Gunnar Kampf, Helmut Sigel, Bernhard Lippert
Zdroj: Chemistry - A European Journal; 2/20/2004, Vol. 10 Issue 4, p1046-1057, 12p
Databáze: Complementary Index