Optimization of properties in a rubber compound containing a ternary polymer blend using response surface methodology.

Autor: Salvatori, Pablo E., Sánchez, Gastón, Lombardi, Aldo, Nicocia, Esteban, Bortolato, Santiago A., Boschetti, Carlos E.
Předmět:
Zdroj: Journal of Applied Polymer Science; 8/10/2018, Vol. 135 Issue 30, p1-1, 9p
Abstrakt: ABSTRACT: In order to find the best combination of three synthetic rubbers, that is, styrene‐butadiene rubber (SBR) grade 1712, SBR grade 1721 and high‐1,4‐cis polybutadiene, that produce a compound with specific end‐use properties, a statistical experimental design is proposed in this work. The design consists of ten mixtures containing specific amounts of total styrene and BR content. A number of properties are tested in each mixture, selecting those related to requirements for the tread of a high performance tire: glass transition temperature (Tg), the ratio between the viscous modulus and the elastic modulus (tanδ@60 °C), Mooney viscosity, and the tensile properties. The values obtained for each property are fit to statistically significant models, obtaining the respective response surfaces. These are next used to define a desirable formulation with the optimal ratio of each rubber, and finally the optimized formulation is validated by comparing the experimental and predicted values for each modeled property. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46548. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index