| Autor: |
Liang, Tao, Hu, Renzong, Zhang, Houpo, Zhang, Hanyin, Wang, Hui, Liu, Jun, Yang, Lichun, Zhu, Min, Ouyang, Yunpeng |
| Zdroj: |
Journal of Materials Chemistry A; 4/28/2018, Vol. 6 Issue 16, p7206-7220, 15p |
| Abstrakt: |
A new ternary SnO2–Co–C composite is produced using a facile and scalable ball milling method, which has a microstructure that includes refined SnO2–Co hybrids embedded in graphite. The Co additives dramatically inhibit Sn coarsening in the lithiated SnO2, which enables highly reversible conversion reactions in the SnO2-based ternary composite during cycling. The electrodes exhibit high ICEs with an average of 80.8% and a reversible capacity of 780 mA h g−1 at 0.2 A g−1 after 400 cycles when the composite was manufactured via small planetary ball milling, and they achieve 875 mA h g−1 after 250 cycles when the material is prepared on a large-scale with a roller mill. Even at a high rate of 2 A g−1, the composite has a long lifetime and delivers 610 mA h g−1 after 1000 cycles. Furthermore, a stable capacity of 410 mA h g−1 can be also retained in a full cell combined with a LiFePO4 cathode and SnO2–Co–C anode when cycling within 2.3–3.4 V at 0.2C. The new ternary SnO2–Co–C composite demonstrates excellent comprehensive electrochemical performances, and it is a promising candidate anode material for use in practical applications. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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