Selenolate Anion as an Organocatalyst: Reactions and Mechanistic Studies.

Autor:	Trofymchuk, Oleksandra S., Zheng, Zhipeng, Kurogi, Takashi, Mindiola, Daniel J., Walsh, Patrick J.
Předmět:	ORGANOCATALYSIS ANIONS DIPHENYL diselenide PHENYL selenide TEMPERATURE effect CHLORIDES
Zdroj:	Advanced Synthesis & Catalysis; 4/17/2018, Vol. 360 Issue 8, p1685-1692, 8p, 1 Diagram, 3 Charts, 1 Graph
Abstrakt:	A new organocatalyst, the selenolate anion [RSe]–, generated from bench-stable and commercially available diphenyl diselenide or from phenyl benzyl selenide (10 mol%) is introduced. Benchmarking is performed in the conversion of benzylic chlorides into trans-stilbenes selectively at room temperature. Mechanistic studies support the intermediacy of the selenolate anion and of 1,2-diphenylethyl phenyl selenide. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
Externí odkaz:	Zobrazit plný text záznamu Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.