The Effect of Uniaxial Pressures on the Infrared Spectra of LiNH4SO4 Crystals.

Autor: Stadnyk, V. I., Rudish, M. Ya., Shchepansky, P. A., Matviishyn, I. M., Gaba, V. M., Gorina, O. M.
Předmět:
Zdroj: Optics & Spectroscopy; Feb2018, Vol. 124 Issue 2, p216-220, 5p
Abstrakt: The infrared reflection spectra of mechanically free and uniaxially compressed LiNH4SO4 crystals are studied for the first time in the spectral range of 800-1700 сm-1 along three crystallophysical directions. The Kramers-Kronig dispersion relations are used to determine the dispersion and baric dependences of refractive index n and the real ε1 and imaginary ε2 parts of the dielectric constant and to calculate the frequencies of longitudinal ωLO and transverse ωТO vibrations, decay constant γ, and oscillator strength f of mechanically free and compressed LiNH4SO4 crystals. The considerable changes observed in the main reflection bands are explained by the effect of uniaxial pressures on the NH4 and SO4 tetrahedra. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index