New Approach to the Synthesis of Symmetrical 1,3-Dichloro-1,1,3,3-Tetraorganyl and 1,1,3,3-Tetrachloro-1,3- Diorganyldisiloxanes.
| Autor: | Basenko, S. V., Maylyan, A. A., Soldatenko, A. S. |
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| Zdroj: | SILICON (1876990X); Mar2018, Vol. 10 Issue 2, p465-470, 6p |
| Abstrakt: | A series of derivatives of symmetrical 1,3- dichloro-1,1,3,3-tetraorganyl- and 1,1,3,3-tetrachloro-1,3- diorganyldisiloxanes ClRR'Si-O-SiRR' (R = Cl, H, CH3; R' = CH3, Et, ClCH2, Vin, Ph) have been synthesized by a novel efficient reaction of corresponding diorganyldichlorosilane and organyltrichlorosilane RSiCl3 (3- 5-fold excess) with dimethyl sulfoxide in 53 to 91 % yield. [ABSTRACT FROM AUTHOR] |
| Databáze: | Complementary Index |
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