| Autor: |
Estrina, G. A., Gur’eva, L. L., Komarov, B. A., Bogdanova, L. M., Kurochkin, S. A., Estrin, Ya. I. |
| Zdroj: |
Polymer Science - Series B; Jan2018, Vol. 60 Issue 1, p1-8, 8p |
| Abstrakt: |
The regularities of formation of the structure of amphiphilic network copolymers on radical copolymerization of N-isopropylacrylamide and polyester dimethacrylate are investigated. The kinetic laws of the consumption of functional groups and the increase in the gel content during formation of a crosslinked product are studied. It is shown that the synthesis of crosslinked amphiphilic copolymers proceeds via competing reactions of N-isopropylacrylamide homopolymerization and its copolymerization with polyester dimethacrylate. With the excess of the monofunctional monomer, a homogeneous rubber-like network copolymer is formed, whereas the excess of the bifunctional reagent results in the morphological inhomogeneity of the reaction product. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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