Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding.

Autor: Sun, Jin-Shi, Jing, Li-Ping, Tian, Yuyang, Sun, Fuxing, Chen, Peng, Zhu, Guangshan
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Zdroj: Chemical Communications; 2/14/2018, Vol. 54 Issue 13, p1603-1606, 4p
Abstrakt: An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. This work gave a perfect example of using PAF70-NH2 as a platform for completely recyclable heterogeneous organocatalysis. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index