Autor: |
Tao, Xin, Daniliuc, Constantin G., Janka, Oliver, Pöttgen, Rainer, Knitsch, Robert, Hansen, Michael Ryan, Eckert, Hellmut, Lübbesmeyer, Maximilian, Studer, Armido, Kehr, Gerald, Erker, Gerhard |
Předmět: |
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Zdroj: |
Angewandte Chemie International Edition; 12/22/2017, Vol. 56 Issue 52, p16641-16644, 4p |
Abstrakt: |
Triplet dioxygen was reduced by TEMPO or trityl radicals in the presence of two molar equivalents of the strong B( p-C6F4X)3 (X: F or H) boron Lewis acids under mild conditions to give the bis(borane)superoxide systems 2. The sensitive radical anion species were isolated and characterized by methods including X-ray crystal structure analysis and EPR spectroscopy. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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