| Autor: |
Cammidge, Andrew N., Turner, Rebecca J., Beskeni, Rhoda D., Almutairi, Tahani |
| Předmět: |
|
| Zdroj: |
Liquid Crystals; Sep/Oct2017, Vol. 44 Issue 12/13, p2018-2028, 11p |
| Abstrakt: |
We report the unexpected observation of columnar mesophase formation in a simple 2,7-dibromotetramethoxytriphenylene – by far the most lightly substituted discotic mesogen in this class. This derivative was prepared alongside the 3,6-dibromotriphenylene isomer to demonstrate an alternative, modified synthetic strategy that permits late-stage interchange of alkyl chain substituents. The new method is employed alongside the original route to deliver several new materials, including a conjugated ferrocene–triphenylene–ferrocene triad, a BODIPY–triphenylene–BODIPY triad and a new nematic twin linked through imine bridges. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
