| Autor: |
Levin, Natalia, Perdoménico, Julián, Slep, Leonardo D., Bill, Eckhard, Weyhermüller, Thomas |
| Předmět: |
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| Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 12/14/2017, Vol. 46 Issue 46, p16058-16064, 7p |
| Abstrakt: |
Photodelivery of NO requires stable compounds which can be made reactive by irradiation with (visible) light. Traditional {MNO}6 complexes require a substantial ligand design to shift their absorption spectra to the appropriate region of the electromagnetic spectrum. [Fe((CH2Py2)2Me[9]aneN3)(NO)](BF4)2 is a new {FeNO}7 octahedral coordination compound, which is thermally and air-stable in solution. Illumination with a 450 nm light source induces significant photodetachment of the coordinated NO (ΦNO = 0.52 mol einstein−1), suggesting that {FeNO}7 compounds can be in fact suitable compounds for therapeutic NO-photorelease. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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