Synthesis and study of optical properties of copolymers of perfluoro-2,2-dimethyl-1,3-dioxole and perfluoro(propyl vinyl ether).

Autor:	Sokolov, V., Boyko, V., Goriachuk, I., Igumnov, S., Molchanova, S., Pogodina, Yu., Polunin, E.
Předmět:	COPOLYMERIZATION OPTICAL properties of metals VINYL ethers MOLECULAR weights OPTICAL fibers X-ray crystallography
Zdroj:	Russian Chemical Bulletin; Jul2017, Vol. 66 Issue 7, p1284-1289, 6p
Abstrakt:	Polymerization under ultrahigh pressure without involvement of initiators was used to synthesize amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole and perfluoro(propyl vinyl ether). The copolymers have molecular masses within 2•10-7•10 au, possess high optical transparency in the telecom ranges of wavelength at 0.85, 1.3, and 1.5 μm and very low refractive index n = 1.293-1.314 at the wavelength λ = 632.8 nm. They can form films and are promising as claddings for optical fibers and waveguides. Amorphous films with the thickness of 1-4 μm were prepared by spin-coating from solutions of the perfluorinated copolymers in perfluorodecalin. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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