| Autor: |
Sakshath, S., Jenni, K., Scherthan, L., Würtz, P., Herlitschke, M., Sergeev, I., Strohm, C., Wille, H.-C., Röhlsberger, R., Wolny, J., Schünemann, V. |
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| Zdroj: |
Hyperfine Interactions; 11/13/2017, Vol. 238 Issue 1, p1-7, 7p |
| Abstrakt: |
A novel sample environment enabling optical pump - nuclear resonance probe experiments has been installed at the beamline P01, Petra III, DESY Hamburg. This set-up has been used to investigate optically induced spin state changes of spin crossover (SCO) complexes by nuclear resonant scattering immediately after excitation by an optical laser pulse. Here, we report the technical details as well as first results of the experiments performed at 290 K and 80 K on the SCO complexes [Fe (NHtrz)]Cl and [Fe(PM-BiA)(NCS)], respectively. The Fe-enriched SCO complexes were excited by a 531 nm laser with a pulse length < 100 ps. Evaluation of the nuclear forward scattering data clearly indicate the presence of high spin (HS) states when the complexes are excited by laser pulses and a pure low spin (LS) state in the absence of any laser pulse. Furthermore, the dependence of the optically excited HS-fraction has been determined as a function of the average optical power. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
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