A Sterically Biased Unsymmetrical Azobenzene Derivative: Synthesis, Molecular Structure, and N NMR Spectroscopic Analysis of ( E)-1-(2,6-Diisopropylphenyl)-2-phenyldiazine.

Autor:	Baumann, David, Erickson, Karla, Scott, Brian, Michalczyk, Ryszard, Silks, L., Kiplinger, Jaqueline
Předmět:	AZOBENZENE derivatives DIAZINES CHEMICAL synthesis MOLECULAR structure NUCLEAR magnetic resonance spectroscopy CRYSTALLOGRAPHY
Zdroj:	Journal of Chemical Crystallography; Dec2017, Vol. 47 Issue 6, p245-248, 4p
Abstrakt:	The title compound, ( E)-1-(2,6-diisopropylphenyl)-2-phenyldiazine (I), was synthesized and characterized using a combination of H, C, and N NMR spectroscopy, infrared and UV/Vis spectroscopy, X-ray crystallography, and GC mass spectrometry. The solid-state structure is also reported. The unsymmetric azobenzene crystallizes in the space group P2/c with unit cell parameters a = 8.001(7) Å, b = 17.827(16) Å, c = 11.129(10) Å, β = 101.960(10)°, V = 1553(2) Å, Z = 4, D = 1.139 g/cm. Graphical Abstract: The synthesis of ( E)-1-(2,6-diisopropylphenyl)-2-phenyldiazine (I) and its characterization using a combination of combination of H, N, and C NMR spectroscopy, infrared and UV/Vis spectroscopy, mass spectrometry, and X-ray crystallography is described in this report. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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