Crystal structure of bis[bis(4-azaniumylphenyl) sulfone] tetranitrate monohydrate.

Autor: Benahsene, Amani Hind, Bendjeddou, Lamia, Merazig, Hocine
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications; 2017, Vol. 73 Issue 11, p1721-1725, 13p, 6 Diagrams, 8 Charts
Abstrakt: In the title compound, the hydrated tetra­(nitrate) salt of dapsone (4,4′-di­amino­diphenyl­sulfone), 2C12H14N2O2S2+·4NO3·H2O {alternative name: bis[bis­(4,4′-di­aza­niumylphen­yl) sulfone] tetra­nitrate monohydrate}, the cations are conformationally similar, with comparable dihedral angles between the two benzene rings in each of 70.03 (18) and 69.69 (19)°. In the crystal, mixed cation–anion–water mol­ecule layers lying parallel to the (001) plane are formed through N—H···O, O—H···O and C—HO hydrogen-bonding inter­actions and these layers are further extended into an overall three-dimensional supra­molecular network structure. Inter-ring π–π inter­actions are also present [minimum ring centroid separation = 3.693 (3) Å]. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index