Synthesis of Ion-exchange Resin for Selective Thorium and Uranyl Ions Sorption.

Autor: Konovalov, Konstantin, Sachkov, Victor
Předmět:
Zdroj: AIP Conference Proceedings; 2017, p1-6, 6p, 2 Color Photographs, 3 Diagrams, 3 Charts
Abstrakt: In this work, the method of ion-exchange resin synthesis selective to radionuclides (uranium and thorium) is presented. The method includes synthesis of polymeric styrene-divinylbenzene macroporous matrix with size of 0.1-0.2 mm, and its subsequent transformation by nitration and then reduction by tin (II) chloride. For passivation of active primary amines partially oxidation by oxygen from air is used. Obtained ion-exchange resin has ratio of sorption sum U+Th to sorption sum of other total rare-earth elements as 1:1.88 at ratio of solid to liquid phase 1:200. The proposed method of ion-exchange resin synthesis is scaled-up for laboratory reactors with volume of 5 and 50 liters. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index