Supramolecular porphyrin-based metal–organic frameworks: Cu(ii) naphthoate–Cu(ii) tetrapyridyl porphine structures exhibiting selective CO2/N2 separation.

Autor: Ohmura, Tetsushi, Setoyama, Norihiko, Mukae, Yusuke, Usuki, Arimitsu, Senda, Shunsuke, Matsumoto, Tsuyoshi, Tatsumi, Kazuyuki
Předmět:
Zdroj: CrystEngComm; 9/21/2017, Vol. 19 Issue 35, p5173-5177, 5p
Abstrakt: 1 and 2 were synthesized through the complexation of 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine with copper(ii) acetate and copper(ii) 1-naphthoate and exhibited two-dimensional open and closed form structures, respectively. X-ray diffraction identified the supramolecular interactions leading to these packing motifs. N2 and CO2 sorption isotherms indicate that 2 allows the separation of these gases. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index