| Autor: |
Satska, Yu., Komarova, N., Gavrilenko, K., Polunin, R., Manoylenko, O., Kolotilov, S. |
| Předmět: |
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| Zdroj: |
Theoretical & Experimental Chemistry; Jul2017, Vol. 53 Issue 3, p204-209, 6p |
| Abstrakt: |
It was shown that the efficiency of chromatographic separation of the racemates of 2-butanol, 2-hexanol, 3-hexanol, and 1-phenylethanol on columns with coordination compounds [Zn(bdc)(S-Lact)(DMF)] (bdc = 1,4-benzenedicarboxylate, S-Lact = (S)-lactate) and Na{(VO)Na(HO)(β-CD)} (β-CD = β-cyclodextrin) does not depend on the size of the alcohol molecule. It was found that in the case of the 1-phenylethanol racemate separation with [Zn(bdc)(S-Lact)(DMF)] the enantiomeric excess of the alcohol varies inversely with the viscosity of the solvent. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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