| Autor: |
Murai, Masahito, Nishiyama, Atsushi, Nishinaka, Naoki, Morita, Haruka, Takai, Kazuhiko |
| Předmět: |
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| Zdroj: |
Chemical Communications; 8/25/2017, Vol. 53 Issue 66, p9281-9284, 4p |
| Abstrakt: |
While cyclopropanes have been explored as synthetically valuable building blocks, their transformation without conjugated substituents or directly substituted heteroatoms remains challenging. The current study describes the iridium-catalysed ring-opening hydrosilylation of cyclopropanes. A nitrogen-based directing group was found to control the reactivity of iridium active species as well as the regiochemistry of carbon–carbon bond cleavage and hydrosilylation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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