Boronic Acid Catalysis for Aza-Piancatelli Rearrangement.

Autor: Wu-Bang Tang, Kou-Sen Cao, Shan-Shui Meng, Wen-Hua Zheng
Předmět:
Zdroj: Synthesis; 2017, Vol. 49 Issue 16, p3670-3675, 6p
Abstrakt: A first example of boronic acid catalyzed intermolecular aza- Piancatelli rearrangement to access a wide range of trans-4,5-disubstituted cyclopentenones is described. The catalytic system can also be extended to intramolecular aza-Piancatelli rearrangement to afford a wide range of azaspirocycles. Good to excellent yields were obtained in an excellent diastereoselective manner. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index