Metal-Free Ammonium Iodide Catalyzed Oxidative Dehydrocoupling of Silanes with Alcohols.

Autor: Yan-qin Yuan, Kumar, Pailla Santhosh, Sheng-rong Guo
Předmět:
Zdroj: Synlett; 2017, Vol. 28 Issue 13, p1620-1623, 4p
Abstrakt: An ammonium iodide catalyzed direct oxidative coupling of silanes with alcohols to give various alkoxysilane derivatives was discovered. tert-Butyl hydroperoxide proved to be an efficient oxidant for this transformation. Attractive features of this protocol include its transition- metal-free nature and the mild reaction conditions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index