Autor: |
Zakaszewska, Anna, Najda-Mocarska, Ewelina, Makowiec, Sławomir |
Předmět: |
|
Zdroj: |
New Journal of Chemistry; 7/21/2017, Vol. 41 Issue 14, p6067-6070, 4p |
Abstrakt: |
Ketenes generated during the thermal decomposition of 5-[(N-aryl/alkylamino)(hydroxyl)methylene]-2,2-dimethyl-1,3-dioxa-4,6-diones react with highly electrophilic iminium ions. The initial [2+2] cycloaddition product rearranges to 2-arylidene malonamide. Mechanistic aspects of the process are presented. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
|