| Autor: |
Loginov, D., Idrisov, V., Nelyubina, Yu., Laskova, Yu., Kudinov, A. |
| Předmět: |
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| Zdroj: |
Russian Chemical Bulletin; Feb2017, Vol. 66 Issue 2, p346-349, 4p |
| Abstrakt: |
A reaction of iodide [(η-indenyl)IrI] ( 1) with thallium dicarbollide Tl[Tl(η-7,8-CBH)] leads to (indenyl)iridacarborane (η-indenyl)Ir(η-7,8-CBH) ( 2) in 32% yield. The X-ray diffraction study showed that in the structure of 2, the five-membered rings C and CB have a cisoid conformation, in which the bridgehead carbon atoms of the indenyl ligand are arranged opposite to the carborane cage carbon atoms. The DFT calculations showed that the Ir-indenyl bond in compound 2 is weaker than the Ir-Cp bond in the complex (η-7,8-CBH)IrCp. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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