Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts.

Autor: Grätz, Maik, Bäcker, Andreas, Vondung, Lisa, Maser, Leon, Reincke, Arian, Langer, Robert
Předmět:
Zdroj: Chemical Communications; 7/7/2017, Vol. 53 Issue 53, p7230-7233, 4p
Abstrakt: We report a novel method for the preparation of PBP-pincer complexes from bis(phosphine)boronium salts. The central (R3P)2HB-moiety in a palladium complex is demonstrated to be a L-type ligand, therewith completing a series of pincer-type complexes with Z-, X- and L-type boron-based ligands, respectively. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index