The Backbone Structure of the Sulfated Galactan from Plocamium costatum (C. Agardh) Hook. f. et Harv. (Plocamiaceae, Rhodophyta).

Autor: Falshaw, R., Furneaux, R. H., Miller, I. J.
Předmět:
Zdroj: Botanica Marina; 1999, Vol. 42 Issue 5, p431-435, 5p
Abstrakt: The polysaccharide extracted from Plocamium costatum has been examined by chemical and spectroscopic techniques. Glycosyl linkage analysis of the native polysaccharide revealed a complex sulfated galactan, but the substitution and linkage pattern was not obvious, partly because the 4-linked units are nearly all 3- sulfated and a high proportion of the 3-linked units are 4-sulfated. Glycosyl linkage and 13C NMR spectro- scopic analysis of a solvolytically desulfated sample, however, confirmed a backbone structure of alternating 3-linked β-D-galactopyranosyl and 4-linked α-galactopyranosyl units as expected for a red algal galactan. The 4-linked galactosyl units, however, are present in both the D- and L-configuration in approximately equal amounts. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index