Mn(OAc)3-Mediated Synthesis of 3-Phosphonyldihydrofurans from β-Ketophosphonates and Alkenes.

Autor: Guozhang Lu, Binzhou Lin, Yuzhen Gao, Jianxi Ying, Guo Tang, Yufen Zhao
Předmět:
Zdroj: Synlett; 2017, Vol. 28 Issue 6, p724-728, 5p
Abstrakt: A new, general method for the synthesis of 3-phosphonyldihydrofuran derivatives has been achieved through Mn(OAc)3-mediated radical cyclization between β-ketophosphonates and alkenes. This transformation allows the direct formation of C-C/C-O bonds and the construction of a dihydrofuran ring in one reaction with operational simplicity and excellent functional-group compatibility. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index