Iodine-mediated $${ sp}^{3}$$ C-H functionalization of methyl ketones: a one-pot synthesis of functionalized indolizines via the 1,3-dipolar cycloaddition reaction between pyridinium ylides and ynones.

Autor: Yavari, Issa, Sheykhahmadi, Jamil, Naeimabadi, Maryam, Halvagar, Mohammad
Zdroj: Molecular Diversity; Feb2017, Vol. 21 Issue 1, p1-8, 8p
Abstrakt: An efficient transition-metal-free approach toward C-H bond activation by using molecular $$\hbox {I}_{2}$$ -mediated $${ sp}^{3}$$ C-H bond functionalization for the synthesis of indolizine derivatives via 1,3-dipolar cycloaddition reaction of nitrogen ylides with ynones is described. Graphical Abstract: [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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