Spectrophotometric determination of boron with an azomethine H derivative.

Autor: Zenki, Michio, Nose, Kazuko, Tôei, Kyoji
Zdroj: Analytical & Bioanalytical Chemistry; Mar1989, Vol. 334 Issue 3, p238-241, 4p
Abstrakt: An azomethine H derivative, 1-(2,4-dihydroxybenzylidene-amino)-8-hydroxynaphthalene-3,6-disulphonic acid (azomethine HR) was examined and proposed as a spectrophotometric reagent for boron, as compared with azomethine H. Azomethine HR reacts with boron in aqueous solution (pH 7.5) to form a yellow complex having an absorption maximum at 425 nm. The sensitivity is 3.5-fold greater than with azomethine H when the same reagent concentration is applied. Basic conditions for the determination of boron have been worked out. The method is applicable to sea and hot spring waters. The standard deviation is ±2.1%. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index