Direct Deposit of Highly Reactive Bi(IO3)3- Polyvinylidene Fluoride Biocidal Energetic Composite and its Reactive Properties.

Autor: Hu, Xiuli, DeLisio, Jeffery B., Li, Xiangyu, Zhou, Wenbo, Zachariah, Michael R.
Předmět:
Zdroj: Advanced Engineering Materials; Jan2017, Vol. 19 Issue 1, pn/a-N.PAG, 9p
Abstrakt: Metal iodate oxidizers are synthesized and evaluated as oxidizers in thermite reactions to generate both heat and a biocidal reaction product for bioagent defeat. TGA/DSC/MS and T-jump TOFMS analysis show gas-phase iodine release from metal iodate decomposition at both low and high heating rates. In constant volume combustion tests, Bi(IO3)3/Al thermite outperforms other metal iodate/Al and traditional thermites. Mechanically sound composites with high mass loadings of particulates are formed by direct electrospray of synthesized metal iodates, nanoaluminum fuel, and polyvinylidine fluoride (PVDF) binder/oxidizer, and burn speeds are measured in both air and argon atmospheres. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index