Autor: |
Piburn, Graham W., Mefford, J. Tyler, Zinni, Nicholas, Stevenson, Keith J., Humphrey, Simon M. |
Předmět: |
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Zdroj: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 1/21/2017, Vol. 46 Issue 3, p977-984, 8p |
Abstrakt: |
Mesoporous LaMnO3 with bulk surface areas in the range 225–300 m2 g−1 were prepared by direct overgrowth around the short-channel version of SBA-15 silica. The extent of LaMnO3 growth was found to be affected by the polarity of solvent system used to impregnate the SBA-15 with La3+ and Mn2+ precursors. The resulting LaMnO3–SiO2 composites were stable in refluxing NaOH, suggesting that the SiO2 was fully encapsulated. The composites were structurally characterized using a range of techniques including 2-D elemental mapping and Raman spectroscopy. The electrochemical behavior of the composites was tested for pseudocapacitance, which revealed normalized specific capacitances over 200 F g−1. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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