Spin-crossover between high-spin (S = 5/2) and low-spin (S = 1/2) states in six-coordinate iron(iii) porphyrin complexes having two pyridine-N oxide derivatives.

Autor:	Ide, Yuki, Murai, Nami, Ishimae, Hiroki, Suzuki, Masaaki, Mori, Shigeki, Takahashi, Masashi, Nakamura, Mikio, Yoshino, Katsumi, Ikeue, Takahisa
Předmět:	IRON porphyrin synthesis PYRIDINE derivatives SPIN crossover
Zdroj:	Dalton Transactions: An International Journal of Inorganic Chemistry; 1/7/2017, Vol. 46 Issue 1, p242-249, 8p
Abstrakt:	In contrast to the general tendency that six coordinate iron(iii) porphyrin complexes with neutral oxygen ligands adopt a high-spin state in a wide range of temperature, some complexes with substituted pyridine N-oxides have exhibited spin-crossover from high-spin to low-spin states with decreasing temperature both in solution and in the solid state. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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