Synthesis and crystal structure determination of the triflate salt of diacetonitrile(2,2′-bipyridine)platinum(II).

Autor:	Field*, J.S., Haines, R.J., Summerton, G.C.
Předmět:	CHEMICAL processes CHEMICAL structure CRYSTALS NITRILES PLATINUM
Zdroj:	Journal of Coordination Chemistry; 9/10/2003, Vol. 56 Issue 13, p1149-1155, 7p, 2 Diagrams, 3 Charts
Abstrakt:	Reaction of [Pt(bipy)Cl 2 ] (bipy = 2,2′-bipyridine) with an excess of silver triflate in refluxing acetonitrile readily affords [Pt(bipy)(MeCN) 2 ](CF 3 SO 3 ) 2 as a yellow, crystalline solid. A single crystal X-ray diffraction study shows that the cations are arranged in a zig-zag manner in rows parallel to the b axis of the monoclinic unit cell. Consideration of the crystal structures of related bipyridyl ligand complexes of platinum(II), leads to the conclusion that a stacked structure with intermolecular Pt…Pt interactions for the title compound is prevented by the electrostatic repulsion between adjacent cations that are doubly charged. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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