| Autor: |
Asari, Naoki, Takemoto, Yusuke, Shinomoto, Yukino, Yagyu, Takuma, Yoshimura, Akira, Zhdankin, Viktor V., Saito, Akio |
| Předmět: |
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| Zdroj: |
Asian Journal of Organic Chemistry; Nov2016, Vol. 5 Issue 11, p1295-1295, 1p |
| Abstrakt: |
The combination of cyclization and fluorination in a single operation provides a straightforward and efficiENt approach to fluorinated heterocycles from unsaturated compounds bearing a heteroatom nucleophile. In this study, a metal ‐ free cycloisomerization–fluorination sequENce of N ‐ propargyl amides catalyzed by an iodine(III) species is reported. The iodine(III) catalyst is in situ gENerated from iodoarENe as a precatalyst with Selectfluor as a fluorinating oxidant in the presENce of HF⋅pyridine. More information can be found in the Communication by Akio Saito et al. on page 1314 in Issue 11, 2016 (DOI: 10.1002/ajoc.201600383). [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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