| Autor: |
Jiang-rong Yang, Sheng-ming Xie, Jun-hui Zhang, Ling Chen, Rui-yu Nong, Li-ming Yuan |
| Předmět: |
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| Zdroj: |
Journal of Chromatographic Science; Oct2016, Vol. 54 Issue 9, p1467-1474, 8p |
| Abstrakt: |
Metal-organic frameworks (MOFs) are a class of novel porous materials consisting of clusters or chains of metal ions and organic linkers. The chiral MOF [Cd(LTP)2]n (LTP = L(-)-thiazolidine-4-carboxylic acid) possesses infinite extension three-dimensional supramolecular reticular structure with right-handed helix. In this work, three capillary columns (A, B and C) containing MOF [Cd(LTP)2]n, permethylated ß- cyclodextrin (CD) and sodium chloride, and MOF [Cd(LTP)2]n and permethylated ß-CD, respectively, have been prepared and their respective enantioseparation abilities have been investigated. The polarities of all of the MOFs and permethylated ß-CDs are moderate. The numbers of theoretical plates (plate m-1) of the three columns have been measured using n-dodecane at 120°C, which followed an increasing order of A (3100) < B (3800) < C (4300). Some racemates were separated with different resolutions on Columns A, B and C. The results indicated that the incorporated MOF [Cd(LTP)2]n enhanced the separations of racemates on a permethylated ß-CD stationary phase with high column efficiency and good reproducibility in gas chromatography. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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