Highly Activated Second-Generation Grubbs-Hoveyda Catalyst Driven by Intramolecular Steric Strain.

Autor: Yuki Kobayashi, Hiroki Miyazaki, Sae Inukai, Chika Takagi, Reo Makino, Kento Shimowaki, Rina Igarashi, Yuya Sugiyama, Shuichi Nakamura, Masato Matsugi
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Zdroj: Synlett; 2016, Vol. 27 Issue 16, p2352-2356, 5p
Abstrakt: Various Grubbs-Hoveyda second-generation catalysts activated by intramolecular steric strain were prepared. The variant bearing a 9-anthracenyl group in the ligand moiety exhibited the highest catalytic activity. The new anthracenyl-type-activated catalyst was used in a ring-closing metathesis reaction to effectively provide a 4-substituted product effectively. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index