| Autor: |
Pal, Raja, Laureanti, Joseph A., Groy, Thomas L., Jones, Anne K., Trovitch, Ryan J. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/4/2016, Vol. 52 Issue 77, p11555-11558, 4p |
| Abstrakt: |
In 5.0 M H2O/acetonitrile, [(Ph2PPrPDI)MoO][PF6]2 produces H2 with 96% Faradaic efficiency at −2.5 V vs. Fc+/0 and a rate of 55 s−1. Reactivity studies and isolation of a Mo(ii) oxo intermediate, (Ph2PPrPDI)MoO, shed light on the H2 evolution mechanism. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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